Publications 2024

A carbene-stabilized diphosphorus: a triple-bonded diphosphorus and a bis(phosphinidene) transfer agent

Joseph S. Yoon, Mehdi Abdellaoui, Milan Gembicky and Guy Bertrand* Chemical Science 2024, 15, 15713-15716.

DOI: 10.1039/D4SC05091F

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Isolation of a pentadienyl-type radical featuring a central secondary carbon

Ying Kai Loh,* Levan Gojiashvili, Mohand Melaimi, Milan Gembicky, Dominik Munz, and Guy Bertrand* Nature Synthesis 2024, 3, 727–731.

DOI: 10.1038/s44160-024-00516-6

Genuine Carbene Versus Carbene-Like Reactivity

Jan Lorkowski, Patrick Yorkgitis, Melinda R Serrato, Milan Gembicky, Cezary Pietraszuk, Guy Bertrand,* and Rodolphe Jazzar* Angew. Chem. Int. Ed. 2024, 63, e202401020.

DOI: 10.1002/anie.202401020

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Cyclic (amino)(barrelene)carbene Ru-complexes: synthesis and reactivity in olefin metathesis

Jakub Talcik, Melinda Serrato, Antonio Del Vecchio, Sophie Colombel-Rouen, Jennifer Morvan, Thierry Roisnel, Rodolphe Jazzar,*   Mohand Melaimi, Guy Bertrand,* and Marc Mauduit* Dalton Trans. 2024, 53, 5346-5350.

DOI: 10.1039/D4DT00102H

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Synthesis of enantiopure 1,2,3-triazolylidene-type mesoionic carbene (MIC) conjugate acids featuring a rigid bicyclic scaffold

Vojtěch Dočekal, Mohand Melaimi, Simona Petrželová, Jan Veselý, Xiaoyu Yan, and Guy Bertrand* Org. Chem. Front. 2024, 11, 2178-2181.

DOI: 10.1039/D4QO00269E

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1H-1,2,3-Triazol-5-ylidenes as Catalytic Organic Single-Electron Reductants

Mehdi Abdellaoui, Kai Oppel, Adam Vianna, Michele Soleilhavoup, Xiaoyu Yan, Mohand Melaimi,* and Guy Bertrand* J. Am. Chem. Soc. 2024, 146, 5, 2933-2938.

DOI: 10.1021/jacs.3c14360

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Ambiphilicity of Ring-Expanded N-Heterocyclic Carbenes

François Vermersch, Victor Wang, Mehdi Abdellaoui, Rodolphe Jazzar,* and Guy Bertrand* Chem. Sci. 2024, 15, 3707-3710.

DOI: 10.1039/D3SC04543A

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