Publications 2019

Understanding the Activity and Enantioselectivity of Acetyl-Protected Aminoethyl Quinoline ligands in Palladium-Catalyzed β-C(sp3)-H Bond Arylation reactions

Erik A Romero, Gang Chen, Milan Gembicky, Rodolphe Jazzar, Jin-Quan Yu, Guy Bertrand J. Am. Chem. Soc. 2019, 141, 16726.

DOI: 10.1021/jacs.9b06746

Mesoionic Carbene (MIC)-Catalyzed H/D Exchange at Formyl Groups

Wei Liu, Liang-Liang Zhao, Mohand Melaimi, Lei Cao, Xingyu Xu, Jean Bouffard, Guy Bertrand, Xiaoyu Yan Chem 2019, 5, 2484.

DOI: 10.1016/j.chempr.2019.08.011

The Debut of Chiral Cyclic (Alkyl)(amino)carbenes (CAACs) in Enantioselective Catalysis

Delphine Pichon, Michele Soleilhavoup, Jennifer Morvan, Glen P. Junor, Thomas Vives, Christophe Crévisy, Vincent Lavallo, Jean-Marc Campagne, Marc Mauduit, Rodolphe Jazzar, Guy Bertrand Chem. Sci. 2019, 10, 7807.

DOI: 10.1039/C9SC028108

Highlights: Chemistry Views , l’Institut de Chimie

Reductive Elimination at Carbon under Steric Control

Daniel Tolentino, Samuel Neale, Connie Isaac, Stuart A. Macgregor, Michael K. Whittlesey, Rodolphe Jazzar, and Guy Bertrand J. Am. Chem. Soc. 2019, 141, 9823

DOI: 10.1021/jacs.9b04957

“Quick-Silver” from a systematic study of highly luminescent, 2-coordinate, d10 coinage metal complexes

Rasha Hamze, Shuyang Shi, Savannah C. Kapper, Daniel Sylvinson Muthiah Ravinson, Laura Estergreen, Moon-Chul Jung, Abegail C. Tadle, Ralf Haiges, Peter I. Djurovich, Jesse L Peltier, Rodolphe Jazzar, Guy Bertrand, Stephen E. Bradforth, Mark E. Thompson J. Am. Chem. Soc. 2019, 141, 8616.

DOI: 10.1021/jacs.9b03657

Silylated Ge9 Clusters as New Ligands for Cyclic (Alkyl)amino and Mesoionic Carbene Copper Complexes

Lorenz J. Schiegerl, Mohand Melaimi, Daniel R. Tolentino, Wilhelm Klein, Guy Bertrand, Thomas F. Fässler Inorg. Chem. 2019, 58, 3256.

DOI: 10.1021/acs.inorgchem.8b03338

Eliminating nonradiativedecay in Cu(I) emitters: > 99%quantum efficiency and microsecond lifetime

Rasha Hamze, Jesse L. Peltier, Daniel Sylvinson, Moonchul Jung, Jose Cardenas, Ralf Haiges, Michele Soleilhavoup, Rodolphe Jazzar, Peter I. Djurovich, Guy Bertrand, Mark E. Thompson Science 2019, 363, 601.

DOI: 10.1126/science.aav2865

Highlights:Science Daily, Eureka Alert, Phys.org, LongRoom, Azooptics

Readily Available Primary Aminoboranes as Powerful reagents for Aldimine Synthesis

Glen Junor, Erik Romero, Xi Chen, Rodolphe Jazzar, Guy Bertrand Angew. Chem. Int. Ed. 2019, 58, 2875. and Angew. Chem. 2019, 131, 2901.

DOI: 10.1002/anie.201814081 and DOI: 10.1002/ange.201814081

Download Raw Data: DFT Data

What Are the Radical Intermediates in Oxidative N-Heterocyclic Carbene Organocatalysis?

Vianney Regnier, Erik A. Romero, Florian Molton, Rodolphe Jazzar, Guy Bertrand, and David Martin J. Am. Chem. Soc. 2019, 141, 1109.

DOI: 10.1021/jacs.8b11824