![Publications 2007
«Thermal valence isomerization of 2,3-diborata-1,4-diphosphoniabuta-1,3-dienes to bicyclo[1.1.0]butanes and cyclobutane-1,3-diyls.»
J.-B. Bourg, A. Rodriguez, D. Scheschkewitz, H. Gornitzka, D. Bourissou, G. Bertrand Angew. Chem. Int. Ed. 2007, 46, 5741-5745.
DOI: 10.1002/anie.200701578

« Facile splitting of hydrogen and ammonia by nucleophilic activation at a single carbon center. »
G. D. Frey, V. Lavallo, B. Donnadieu, W. W. Schoeller, G. Bertrand Science 2007, 316, 439-441.
DOI: 10.1126/science.1141474

« Synthesis and reactivity of olefin metathesis catalysts bearing cyclic (alkyl)(amino)carbene. »
D. R. Anderson, V. Lavallo, D. J. O’leary, G. Bertrand, R. H. Grubbs Angew. Chem. Int. Ed. 2007, 46, 7262-7265.
DOI: 10.1002/anie.200702085

« Recently reported crystalline isothiazole carbenes: myth or reality? »
A. Dehope, V. Lavallo, B. Donnadieu, W. W. Schoeller, G. Bertrand Angew. Chem. Int. Ed. 2007, 46, 6922-6925.
DOI: 10.1002/anie.200702272

« Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenes. »
V. Lavallo, G. D. Frey, S. Kousar, B. Donnadieu, G. Bertrand Proc. Natl. Acad. Sci. USA 2007, 104, 13569-13573.
10.1073/pnas.0705809104
« Carbene activation of P4 and subsequent derivatization. »
J. D. Masuda, W. W. Schoeller, B. Donnadieu, G. Bertrand Angew. Chem. Int. Ed. 2007, 46, 7052-7055.
DOI: 10.1002/anie.200703055

« Synthesis of a mixed phosphonium - sulfonium bis-ylide R3P=C=SR2. »
S. Pascual, M. Asay, O. Illa, T. Kato, G. Bertrand, N. Saffon-Merceron, V. Branchadell, A. Baceiredo Angew. Chem. Int. Ed. 2007, 46, 9078-9080.
DOI: 10.1002/anie.200704071

« NHC-mediated aggregation of P4: isolation of a P12 cluster. »
J. D. Masuda, W. W. Schoeller, B. Donnadieu, G. Bertrand J. Am. Chem. Soc. 2007, 129, 14180-14181.
DOI: 10.1021/ja077296u

« Transient palladadiphosphanylcarbenes: singlet carbenes with an “inverse” electronic configuration and unusual transannular metal-carbene interactions (pCPd donation and sPdC back-donation). »
J. Vignolle, H. Gornitzka, L. Maron, W. W. Schoeller, D. Bourissou, G. Bertrand J. Am. Chem. Soc. 2007, 129, 978-985.
DOI: 10.1021/ja066738j

« Transient amino-hydrazino-carbenes: a radical pathway for intramolecular 1,2-migration reactions. »
X. Cattoen, H. Gornitzka, F. S. Tham, K. Miqueu, D. Bourissou, G. Bertrand Eur. J. Org. Chem. 2007, 912-917.
DOI: 10.1002/ejoc.200600901

« An unusual norcaradiene/tropylium rearrangement from a persistent amino-phosphonio-carbene. »
J. Vignolle, B. Donnadieu, D. Bourissou, G. Bertrand Tetrahedron Lett. 2007, 48, 685-687.
DOI: 10.1016/j.tetlet.2006.11.099

« Intramolecular “hydro-iminiumation” of alkenes: application to the synthesis of conjugate acids of cyclic (alkyl)(amino)carbenes. »
R. Jazzar, R. D. Dewhurst, J.-B. Bourg, B. Donnadieu, Y. Canac, G. Bertrand Angew. Chem. Int. Ed. 2007, 46, 2899-2902.
DOI: 10.1002/anie.200605083

« Intramolecular “hydro-iminiumation and -amidiniumation” of alkenes: a convenient, flexible and scalable route to cyclic iminium and imidazolinium salts. »
R. Jazzar, J.-B. Bourg, R. D. Dewhurst, B. Donnadieu, G. Bertrand J. Org. Chem. 2007, 72, 3492-3499.
DOI: 10.1021/jo0703909

« Synthesis of the first phospha-formamidines and phospha-formamidinates. »
M. Song, B. Donnadieu, M. Soleilhavoup, G. Bertrand Chem. Asian J. 2007, 2, 904-908.
DOI: 10.1002/asia.200700103

« Stable P-heterocyclic carbenes (PHCs): scope and limitations. »
J. D. Masuda, D. Martin, C. Lyon-Saunier, A. Baceiredo, H. Gornitzka, B. Donnadieu, G. Bertrand Chem. Asian J. 2007, 2, 178-187.
DOI: 10.1002/asia.200600300
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