Publications 2007

  
«Thermal valence isomerization of 2,3-diborata-1,4-diphosphoniabuta-1,3-dienes to bicyclo[1.1.0]butanes and cyclobutane-1,3-diyls.» 
J.-B. Bourg, A. Rodriguez, D. Scheschkewitz, H. Gornitzka, D. Bourissou, G. Bertrand Angew. Chem. Int. Ed. 2007, 46, 5741-5745.
DOI: 10.1002/anie.200701578



« Facile splitting of hydrogen and ammonia by nucleophilic activation at a single carbon center. » 
G. D. Frey, V. Lavallo, B.  Donnadieu, W. W. Schoeller, G. Bertrand Science 2007, 316, 439-441.
DOI: 10.1126/science.1141474




« Synthesis and reactivity of olefin metathesis catalysts bearing cyclic (alkyl)(amino)carbene. » 
D. R. Anderson, V. Lavallo, D. J. O’leary, G. Bertrand, R. H. Grubbs Angew. Chem. Int. Ed. 2007, 46, 7262-7265. 
DOI: 10.1002/anie.200702085



« Recently reported crystalline isothiazole carbenes: myth or reality? » 
A. Dehope, V. Lavallo, B. Donnadieu, W. W. Schoeller, G. Bertrand Angew. Chem. Int. Ed. 2007, 46, 6922-6925.
DOI: 10.1002/anie.200702272



« Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenes. » 
V. Lavallo, G. D. Frey, S.  Kousar, B. Donnadieu, G. Bertrand Proc. Natl. Acad. Sci. USA 2007, 104, 13569-13573.
10.1073/pnas.0705809104

« Carbene activation of P4 and subsequent derivatization. » 
J. D. Masuda, W. W. Schoeller, B. Donnadieu, G. Bertrand Angew. Chem. Int. Ed. 2007, 46, 7052-7055.
DOI: 10.1002/anie.200703055



« Synthesis of a mixed phosphonium - sulfonium bis-ylide R3P=C=SR2. » 
S. Pascual, M. Asay, O. Illa, T. Kato, G. Bertrand, N. Saffon-Merceron, V. Branchadell, A. Baceiredo Angew. Chem. Int. Ed. 2007, 46, 9078-9080. 
DOI: 10.1002/anie.200704071



« NHC-mediated aggregation of P4: isolation of a P12 cluster. » 
J. D. Masuda, W. W. Schoeller, B. Donnadieu, G. Bertrand J. Am. Chem. Soc. 2007, 129, 14180-14181.
DOI: 10.1021/ja077296u



« Transient palladadiphosphanylcarbenes: singlet carbenes with an “inverse” electronic configuration and unusual transannular metal-carbene interactions (pCPd donation and sPdC back-donation). » 
J. Vignolle, H. Gornitzka, L. Maron, W. W. Schoeller, D. Bourissou, G. Bertrand J. Am. Chem. Soc. 2007, 129, 978-985.
DOI: 10.1021/ja066738j



« Transient amino-hydrazino-carbenes: a radical pathway for intramolecular 1,2-migration reactions. » 
X. Cattoen, H. Gornitzka, F. S. Tham, K. Miqueu, D. Bourissou, G. Bertrand Eur. J. Org. Chem. 2007, 912-917.
DOI: 10.1002/ejoc.200600901



« An unusual norcaradiene/tropylium rearrangement from a persistent amino-phosphonio-carbene. » 
J. Vignolle, B.  Donnadieu, D. Bourissou, G. Bertrand Tetrahedron Lett. 2007, 48, 685-687.
DOI: 10.1016/j.tetlet.2006.11.099



« Intramolecular “hydro-iminiumation” of alkenes: application to the synthesis of conjugate acids of cyclic (alkyl)(amino)carbenes. » 
R. Jazzar, R. D. Dewhurst, J.-B. Bourg, B.  Donnadieu, Y. Canac, G. Bertrand Angew. Chem. Int. Ed. 2007, 46, 2899-2902.
DOI: 10.1002/anie.200605083



« Intramolecular “hydro-iminiumation and -amidiniumation” of alkenes: a convenient, flexible and scalable route to cyclic iminium and imidazolinium salts. » 
R. Jazzar, J.-B. Bourg, R. D. Dewhurst, B.  Donnadieu, G. Bertrand J. Org. Chem. 2007, 72, 3492-3499.
DOI: 10.1021/jo0703909



« Synthesis of the first phospha-formamidines and phospha-formamidinates. » 
M. Song, B.  Donnadieu, M. Soleilhavoup, G. Bertrand Chem. Asian J. 2007, 2, 904-908.
DOI: 10.1002/asia.200700103



« Stable P-heterocyclic carbenes (PHCs): scope and limitations. » 
J. D. Masuda, D. Martin, C. Lyon-Saunier, A. Baceiredo, H. Gornitzka, B.  Donnadieu, G. Bertrand Chem. Asian J. 2007, 2, 178-187.
DOI: 10.1002/asia.200600300



http://onlinelibrary.wiley.com/doi/10.1002/anie.200701578/abstracthttp://www.sciencemag.org/content/316/5823/439http://onlinelibrary.wiley.com/doi/10.1002/anie.200702085/abstracthttp://onlinelibrary.wiley.com/doi/10.1002/anie.200702272/abstracthttp://www.pnas.org/content/104/34/13569.abstracthttp://onlinelibrary.wiley.com/doi/10.1002/anie.200703055/abstracthttp://onlinelibrary.wiley.com/doi/10.1002/anie.200704071/abstracthttp://pubs.acs.org/doi/abs/10.1021/ja077296uhttp://pubs.acs.org/doi/abs/10.1021/ja066738jhttp://onlinelibrary.wiley.com/doi/10.1002/ejoc.200600901/abstracthttp://dx.doi.org/10.1016/j.tetlet.2006.11.099http://onlinelibrary.wiley.com/doi/10.1002/anie.200605083/abstracthttp://pubs.acs.org/doi/abs/10.1021/jo0703909http://onlinelibrary.wiley.com/doi/10.1002/asia.200700103/abstracthttp://onlinelibrary.wiley.com/doi/10.1002/asia.200600300/abstractshapeimage_1_link_0shapeimage_1_link_1shapeimage_1_link_2shapeimage_1_link_3shapeimage_1_link_4shapeimage_1_link_5shapeimage_1_link_6shapeimage_1_link_7shapeimage_1_link_8shapeimage_1_link_9shapeimage_1_link_10shapeimage_1_link_11shapeimage_1_link_12shapeimage_1_link_13shapeimage_1_link_14

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