Dr. Rodolphe Jazzar
Research Director (CNRS)
Address : University of California, San Diego, 5213 Pacific Hall, Department of Chemistry, 9500 Gilman Dr., La Jolla, CA 92093-0358
E-mail: rjazzar@ucsd.edu
Phone number : (858) 534 5732
ORCID: 0000-0002-4156-7826
1) Absolute Templating of M(111) Cluster Surrogates by Galvanic Exchange Peltier, J. L.; Soleilhavoup, M.; Martin, D.; Jazzar, R.; Bertrand, G. J. Am. Chem. Soc. 2020, 142, 16479-16485.
2) The influence of C(sp3)H‐Selenium Interactions on the 77 Se NMR Quantification of the π‐Accepting Properties of Carbenes Junor, G. P.;# Lorkowski, J.;# Weinstein, C. M.; Jazzar, R.; Pietraszuk, C.; Bertrand, G. Angew. Chem. Int. Ed. 2020, 59, 22212-22217.
3) Reductive Elimination at Carbon under Steric Control Tolentino, D., Neale, S. Isaac, C., Macgregor, S., Whittlesey, M., Jazzar, R., Bertrand, G. J. Am. Chem. Soc. 2019, 141, 9823-9826.
4) Readily Available Primary Aminoboranes as Powerful Reagents for Aldimine Synthesis Junor, G. P., Romero, E. A., Chen, X., Jazzar, R., Bertrand, G. Angew. Chem. Int. Ed. 2019, 58, 2875.
5) Tandem copper hydride–Lewis pair catalyzed reduction of carbon dioxide into formate with dihydrogen Romero, E. A., Zhao, T. X., Hu, X. B., Wu, Y. T., Jazzar, R., Bertrand, G.Nature Catal. 2018, 1, 743.
B.Sc. (1998) Université de Poitiers, France
M.Sc. (1999) Pr. S. Higgins, University of Liverpool, UK
Ph.D. (2003) Pr. M. Whittlesey, University of Bath, UK
Postdoc. (2003-2005) Pr. E. P. Kundig, University of Geneva, Switzerland
Postdoc. (2005-2006) Pr. G. Bertrand, University of California Riverside, USA
Postdoc. (2006-2008) Pr. O. Baudoin, University Claude Bernard Lyon, France
Appointed CNRS Research Associate (CR1-2008) working with Pr. O. Baudoin, University Claude Bernard, Lyon, France
HDR. (2013) French Research Habilitation Diploma
CNRS Research Associate (CR1-2014) working with Pr. G. Bertrand, University of San Diego California, USA
In situ monitoring of reaction kinetics (NMR, IR, UV), isolation of catalytic intermediates, and their implication in said catalytic systems are powerful experimental tools which provide a wealth of information. Using experimental and theoretical studies, we have shown that these techniques not only allow us to decipher complex catalytic reactions, (thereby aiding in the improvements of known systems: Pd catalysed C(sp3-H) activations, alpha-arylations…); but more importantly can be used to deviate from well-established processes (Pd catalysed remote arylations, Cu catalysed dehydroborylation…). Recently, we extended this strategy to non-metal mediated transformations, which allowed us to discover a novel synthetic methodology for the preparation of aldimines.
Contact us :
UCSD-CNRS joint chemistry lab - UMI 3555
Address : University of California, San Diego, 5213 Pacific Hall, Department of Chemistry, 9500 Gilman Dr., La Jolla, CA 92093-0358
e-mail : guybertrand@ucsd.edu
Phone number : (858) 534 5412
Financial support :
