Dr. Michèle Soleilhavoup
Research Associate (CNRS)
Address : University of California, San Diego, 5213 Pacific Hall, Department of Chemistry, 9500 Gilman Dr., La Jolla, CA 92093-0358
E-mail: msoleilhavoup@ucsd.edu
ORCID: 0000-0001-5339-921X
Dr. Michèle Soleilhavoup
Research Associate (CNRS)
Address : University of California, San Diego, 5213 Pacific Hall, Department of Chemistry, 9500 Gilman Dr., La Jolla, CA 92093-0358
E-mail: msoleilhavoup@ucsd.edu
ORCID: 0000-0001-5339-921X
B.Sc. (1989) University Paul Sabatier, Toulouse, France
M.Sc. Chemistry (Pr. G. Bertrand) (DEA) (1989) University Paul Sabatier, Toulouse, France
Ph.D. Chemistry (Pr. G. Bertrand) (1993) Laboratoire de Chimie de Coordination, Toulouse, France
Postdoc (1993 - 1995) BASF AG, Ludwigshafen, Germany
Research Associate CNRS (1995 - 1998) University Pierre et Marie Curie (Paris VI) UMR 7611. Prof. E Rose, Paris, France
Research Associate CNRS (1999) Sanofi-Synthelabo Research Center, Toulouse, France
Research Associate CNRS (2000 - 2001) Laboratoire de Chimie de Coodination UPR 8241, Prof. R Chauvin, Toulouse, France
Research Associate CNRS (2001 - 2012) University of California Riverside, UCR/CNRS Joint Research Laboratory, UMI 2957. Prof. G Bertrand, Riverside, CA, USA
Research Associate CNRS (2012 - Present) University of California San Diego, UCSD/CNRS Joint Research Laboratory, UMI 3555. Prof. G Bertrand, La Jolla, CA, USA
During my Ph.D. thesis, I focused on the stabilization of transient carbenes and other unstable species using main group elements (P, Si, B…).
During my industrial postdoctoral experience, I’ve been working on the synthesis of new metallocene catalysts and their application in polymerization processes.
My first CNRS position gave me the opportunity to work on porphyrin chemistry, especially the synthesis of biomimetic heme precursors.
The Sanofi-Synthelabo Research Center offered me a one year position to develop a combinatorial chemistry approach of Mannich type reactions.
With prof. Remi Chauvin in Toulouse, I was in charge of developing the new concept of « carbo-meric molecules. » More than carbon-rich, carbo-mers are carbon-enriched molecules obtained by formal insertion of C2 units into each or part of the bonds of a given molecule. The original optical, chromophoric, and redox properties of these three-folds expanded molecules are studied and systematically compared with those of their parents.
Since 2001, I am working with Prof. Guy Bertrand, first at UCR and now at UCSD. I am involved in different projects including the synthesis of stable carbenes and the design of original ligands to be used in coordination chemistry.
Selected Publications
Spectroscopic Evidence for a Monomeric Copper(I) Hydride and Crystallographic Characterization of a Monomeric Silver(I) Hydride E. Romero, P. M. Olsen, R. Jazzar, M. Soleilhavoup, M. Gembicky, G. Bertrand Angew. Chem. Int. Ed. 2017, 56, 4024.
Eliminating nonradiative decay in Cu(I) emitters: > 99% quantum efficiency and microsecond lifetime R. Hamze, J. L. Peltier, D. Sylvinson, M. Jung, J. Cardenas, R. Haiges, M. Soleilhavoup, R. Jazzar, P. I. Djurovich, G. Bertrand, M. E. Thompson Science 2019, 363, 601. DOI: 10.1126/science.aav2865
The debut of chiral cyclic (alkyl)(amino)carbenes (CAACs) in enantioselective catalysis D. Pichon, M. Soleilhavoup, J. Morvan, G. P. Junor, T. Vives, C. Crevisy, V. Lavallo, J-M. Campagne, M. Mauduit, R. Jazzar, G. Bertrand Chem. Sci. 2019, 10, 7807. DOI: 10.1039/C9SC02810B
Stable Carbenes, Nitrenes, Phosphinidenes, and Borylenes: Past and Future. M. Soleilhavoup, G. Bertrand. Chem 2020, 6, 1275. DOI: 10.1016/j.chempr.2020.04.015
Absolute Templating of M(111) Cluster Surrogates by Galvanic Exchange. J. Peltier, M. Soleilhavoup, D. Martin, R. Jazzar, G. Bertrand. J. Am. Chem. Soc. 2020, 142, 16479. DOI: 10.1021/jacs.0c07990
Contact us :
UCSD-CNRS joint chemistry lab - UMI 3555
Address : University of California, San Diego, 5213 Pacific Hall, Department of Chemistry, 9500 Gilman Dr., La Jolla, CA 92093-0358
e-mail : guybertrand@ucsd.edu
Phone number : (858) 534 5412
Financial support :
Biography
Research Interests